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  Inorganic Chemistry

XENON OXYDIFLUORIDE :

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Xenon oxydifluoride (XeOF2) is formed by partial hydrolysis of XeF4 at 193 K,

                    193 K
XeF4 + H2O ———> XeOF2 + 2HF.

Structure : XeOF2 has trigonal bipyramid geometry due to sp3 d-hybridization of Xe. Two equatorial positions are occupied by lone pairs of electrons giving a T-shape to the molecule. There is one Xe–O double bond containing pπ–dπ overlapping.

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