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  Inorganic Chemistry

PHYSICAL PROPERTIES OF NITROGEN :

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N2 is a colorless, odorless and tasteless gas. It is a non-toxic gas. It’s vapor density is 14. It has very low solubility in water.

CHEMICAL PROPERTIES OF NITROGEN

(1) N2 is neutral towards litmus. It is chemically unreactive at ordinary temp. It is neither combustible nor it supports combustion.

(2) The N – N bond in N2 molecule is a triple bond ( N ≡ N ) with a bond distance of 109.8 pm and bond dissociation energy of 946 kJ mol-1

(3) Combination with compounds : N2 combines with certain compounds on strong heating . eg

                   1300K
CaC2 + N2 ———→ CaCN2 + C
Calsium carbide calsium cyanamide
                   2100K
AI2O3 + N2 ———→ 2AIN + 2CO
Aluminium oxide          Al.nitride

Both these compounds are hydrolysed on boiling with water to give ammonia.

CaCN2 + 3H2O ———→ CaCO3 + 2NH3

AIN + 3H2O ———→ AI ( OH )3 + NH3

Therefore, calcium cyanamide is used as a fertilizer under the name nitrolim ( CaCN2 + C )

USES OF NITROGEN :

N2 is mainly used in the manufacture of compounds like NH3, HNO3, CaCN2 etc.


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