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  Inorganic Chemistry

NITROGEN FAMILY :

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Nitrogen is the first member of group 15 or VA of the periodic table. It consists of five elements nitrogen (N), phosphorus (P), arsenic (As), antimony (Sb) and bismuth (Bi). The elements of this group are collectively called pnicogens and their compounds as pniconides. The name is derived from Greek word “Pniomigs” meaning suffocation. Pniconide contain M3– species.

(1) Electronic configuration

Elements

Electronic configuration (ns2 np3 )

7N

[He] 2s22p3

15P

[Ne] 3s23p3

33As

[Ar] 3d104s24p3

51Sb

[Kr] 4d105s25p3

83Bi

[Xr] 4f1454106s26p3

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