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  Inorganic Chemistry

LEAD TETRACHLORIDE, PBCL4 :

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It is obtained by heating of PbO2 with conc. HCl .

It is a yellow oily fuming liquid which decomposes into PbCl2 at 373 K .

            373 K
PbCl4 ———> PbCl2 + Cl2

It also combines with HCl to form complex hexachloroplumbate (IV) ion.

PbCl4 + 2 HCl ——> H2 [PbCl6]


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