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  Inorganic Chemistry

Compounds Of Aluminum :

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(i) Aluminum oxide or Alumina ( AI2O3)

It occurs in nature as colorless corundum and several colored minerals like ruby (red), topaz (yellow), Sapphire (blue), amethyst (violet) and emerald (green). These minerals are used as precious stones (gems).

(ii) Aluminum chloride ( AI2CI6 ) : It is prepared by passing dry chlorine over aluminum powder.

AI2O3 + 3C + 3CI2 —→ 2AICI3 + 3CO(g)
                                      (anhydrous)

It exists as dimer AI2CI6 in inert organic solvents and in vapor state. It sublimes at 100oc under vacuum. Dimeric structure disappears when AICI3 is dissolved in water. It is hygroscopic in nature and absorbs moisture when exposed to air.

(iii) Thermite : A mixture of aluminum powder and Fe2O3 in the ratio 1:3. It is used for welding of iron. The reaction between AI and Fe2O3 is highly exothermic,

AI + Fe2O3→ AI2O3 + Fe Heat

(iv) Aluminium sulphate [Al2(SO4)3] : It is used for the preparation of alums e.g., potash alum AI2 ( SO4 )3 . K2SO4 . 24H2O . It is also used for making fire proof clothes.


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