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  Inorganic Chemistry

Bond Dissociation Energy & Bond Length :

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Bond dissociation energy : Bond dissociation energies of chlorine, bromine and iodine decrease down the group as the size of the atom increases. The bond dissociation energy of fluorine, is however, lower than those of chlorine and bromine because of inter electronic repulsions present in the small atom of fluorine

X2

F2

Cl2

Br2

I2

Bond dissociation energy (kJ mol–1)

158

243

192

151

Hence bond energy decreases in the order Cl2 > Br2 > F2 > I2

Bond length in X2 molecule : As the size of the halogen atom increase, the bond length of X — X bond in X2 molecule increases from F2 to I2

X–X bond

F–F

Cl–Cl

Br–Br

I–I

Bond length (pm)

143

199

228

266

Thus, the bond length increases in the order F2 < Cl2 < Br2 < I2.


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