Bond dissociation energy : Bond dissociation energies of chlorine, bromine and iodine decrease down the group as the size of the atom increases. The bond dissociation energy of fluorine, is however, lower than those of chlorine and bromine because of inter electronic repulsions present in the small atom of fluorine
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Bond dissociation energy (kJ mol–1) |
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Hence bond energy decreases in the order Cl2 > Br2 > F2 > I2
Bond length in X2 molecule : As the size of the halogen atom increase, the bond length of X — X
bond in
X2 molecule increases from
F2 to I2
Thus, the bond length increases in the order
F2 < Cl2 < Br2 < I2. |